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In these cases, she believes in No Excuse. "I'm terribly sorry, but that night is impossible for me" can mean that you had already planned to be making a public fool of yourself for all to see, so you have nothing (else) to be ashamed of if caught.
Gentle Reader: In some societies, it is. Elaborate conventions exist to enable people to field or ignore a request so as to make clear that it has been refused -- while also conveying how much pain it costs to refuse.
We don't go in for that sort of subtlety; we pride ourselves on our frankness. Yet Miss Manners is amazed and touched that in a society that suffers from only-too-straightforward communication, often in the form of a raised finger, many people still feel that it is rude to refuse any request. Also, they think they have to supply an excuse, which will be led into a tangle of implausible lies.
So they hedge. As you have noticed, this causes more trouble to those who mistakenly think their requests have been granted, than if they were refused outright.
The polite way to refuse is to precede the denial with an apology but no excuse: "Oh, I'm terribly sorry, but I can't." "I'd love to, but I'm afraid it's impossible." "Unfortunately, I can't, but I hope you can find someone."
It is not more polite to say, "Well, sure, if I can finish up my other stuff and I don't have another assignment, only my stepson may be in town then and I'm having trouble with my car, so I don't know."